PM10 EXCEEDANCE IN BULGARIA

Iliyana Naydenova, Tsvetelina Petrova, Rositsa Velichkova, Iskra Simova

Abstract


Despite the effort done by member states during the last decade, failure in the implementation of the Ambient Air Quality Directive is being continuously registered in many European cities for different air pollutants. One of the biggest concerns in Bulgaria is the exceeded PM10 concentration in the ambient air, measured in all six air quality zones during the winter period. This has induced numerous activities (at the national and European level) focused on the following issues: identification of the level of exceedance of the air quality norms for PM10; the general emission sources; the most prominent omissions and discrepancies in the legislative framework; the level of implementation of the prescribed measures and many others. However, the PM10 exceedance is still of a significant concern in at least 28 municipalities in Bulgaria. Thus, the present work introduces a brief report on the current state of the problem in the country. For that purpose, benchmarking analyses was applied for obtaining the range of discrepancies and the tendencies of the PM10 concentrations, monitored in the ambient air at the affected municipalities. The investigation was carried out using merely officially reported and freely accessible data and covered a relatively short period of time of six years. The latest national and European environmental reports present data confirming the primary role of residential heating and transport during the winter period as well as at the occurrence of particular atmospheric conditions.

Keywords


particulate matter, PM10, ambient air quality

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References


EEA (2017) Emissions of the main air pollutants in Europe. Report. https://www.eea.europa.eu/data-and-maps/indicators/main-anthropogenic-air-pollutant-emissions/assessment-5.

Schmidt, K.-G. and Zellner R. (2010, September) Feinstaub, Statuspapier. ISBN: 978-3-89746-120-8, https://dechema.de/dechema_media/Statuspapier_Feinstaub-p-3396-view_image-1-called_by-dechema-original_site-dechema_eV-original_page-124930.pdf.

Dimitriou, K., & Kassomenos, P. (2017) Airborne heavy metals in two cities of North Rhine Westphalia - Performing inhalation cancer risk assessment in terms of atmospheric circulation. Chemosphere, 186, 78-87. http://dx.doi.org/10.1016/j.chemosphere.2017.07.138.

Colom-Díaz, J.M., Alzueta, M. U., Fernandes, U., Costa, M. (2017) Emissions of polycyclic aromatic hydrocarbons during biomass combustion in a drop tube furnace. Fuel 207, 790–800 http://dx.doi.org/10.1016/j.fuel.2017.06.084.

WHO (2005) Air quality guidelines for particulate matter, ozone, nitrogen dioxide and sulfur dioxide. Global update 2005. Summary of risk assessment. http://apps.who.int/iris/bitstream/handle/10665/69477/WHO_SDE_PHE_OEH_06.02_eng.pdf;jsessionid=F9E51C972E6B82306A175191188E88F4?sequence=1.

Directive 2008/50/EC of the European Parliament and of the Council, of 21 May 2008, on ambient air quality and cleaner air for Europe. https://eur-lex.europa.eu/legal-content/en/ALL/?uri=CELEX:32008L0050.

EEA (2015) Exceedance of air quality standards in urban areas. Report. https://www.eea.europa.eu/data-and-maps/indicators/exceedance-of-air-quality-limit-3/assessment.

Megido, L., Suarez-Pena, B., Negral L., Castrillon, L., Suarez, S. Fernandez-Nava, Y. and Maranon E. (2016) Relationship between physico-chemical characteristics and potential toxicity of PM10. Chemosphere 162, 73-79. http://dx.doi.org/10.1016/j.chemosphere.2016.07.067.

Chernyshev, V.V., Zakharenko, A.M., Ugay, S.M., Hien, T.T., Hai, L.H., Kholodov, A.S., Burykina, T.I., Stratidakis, A.K., Mezhuev, Ya O., Tsatsakis, A.M., Golokhvast, K.S. (2018) Morphologic and chemical composition of particulate matter in motorcycle engine exhaust. Toxicology Reports 5, 224–230. http://dx.doi.org/10.1016/j.toxrep.2018.01.003.

Czech, H., Miersch, T., Orasche, J., Abbaszade, G., Sippula, O., Tissari, J., Michalke, B., Schnelle-Kreis, J., Streibel, Th., Jokiniemi, J., Zimmermann, R. (2018) Chemical composition and speciation of particulate organic matter from modern residential small-scale wood combustion appliances. Science of the Total Environment 612, 636–648 http://dx.doi.org/10.1016/j.scitotenv.2017.08.263.

NRSPE (2017) National Report on the Status and the Protection of the Environment of Bulgaria 2017 http://eea.government.bg/bg/soer/2015.

European Commission (EC) - Press release (2018) Air quality: Commission takes action to protect citizens from air pollution, Brussels, 17 May 2018, http://europa.eu/rapid/press-release_IP-18-3450_en.htm.

EEA (2017a), Air pollutant emissions data viewer 2017 https://www.eea.europa.eu/data-and-maps/dashboards/air-pollutant-emissions-data-viewer.

IIR (2017) Bulgaria’s Informative Inventory Report 2017, http://eea.government.bg/bg/dokladi/clrtap.

IIR (2018) Bulgaria’s Informative Inventory Report 2018, http://www.ceip.at/ms/ceip_home1/ceip_home/status_reporting/2018_submissions/.

NFR tables (2017) National Inventory on Air Pollutants reported as NFR tables, 2017, http://www.ceip.at/ms/ceip_home1/ceip_home/status_reporting/2017_submissions/.

NFR tables (2018) National Inventory on Air Pollutants reported as NFR tables, 2018, http://www.ceip.at/ms/ceip_home1/ceip_home/status_reporting/2018_submissions/.

Directive 2016/2284/EU of the European Parliament and of the Council of 14 December 2016 on the reduction of national emissions of certain atmospheric pollutants, amending Directive 2003/35/EC and repealing Directive 2001/81/EC, https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=uriserv%3AOJ.L_.2016.344.01.0001.01.ENG.

Tista, M., Wankmueller, R., Marecko, K. (2017) Methodologies applied to the CEIP GNFR gap-filling (2017) Part III: Main pollutants and Particulate Matter (NOx, NMVOCs, SOx, NH3, CO, PM2.5, PM10, PMcoarse). CEIP Umweltbundesamt, Technical report CEIP 03-3/2017, http://www.ceip.at/fileadmin/inhalte/emep/pdf/2017/MAIN___PM_gap-filling_documentation_2017.pdf.

ETC/ACM (2013, November) How to start with PM modeling for air quality assessment and planning relevant to the Air Quality Directive. ETC/ACM Technical Paper 2013/11, ETCACM_TP_2013_11_FAIRMODE_guide_modelling_PM.pdf.

Ministry of Environment and Water of Bulgaria (MOEW), http://www.moew.government.bg/bg/vuzduh/kachestvo-na-atmosferniya-vuzduh/normativni-aktove/.

Environment and Water Executive Agency (ExEA), http://eea.government.bg/bg/dokladi.

EMEP/EEA (2016) air pollutant emission inventory guidebook, https://www.eea.europa.eu/publications/emep-eea-guidebook-2016.

Baumbach, G., Baumann, K., Droescher, F., Gross, H., Steisslinger, B. (1990) Luftreinhaltung, Enstehung, Ausbreitung und Wirkung von Luftreinigungen-Messtechnik, Emissionsminderung und Vorschriften, Springer-Verlag Berlin Heidelberg New York, ISBN 3-540-52677-3.

Warnatz, J., Maas, U., Dibble, R.W. (2006) Physical and chemical fundamentals, modeling and simulation, experiments, pollutant formation, 4th Edition. Springer-Verlag Berlin, Heidelberg, ISBN-10 3-540-25992-9 and ISBN-13 978-3-540-25992-3.

Agafonov, G.L., Naydenova, I., Vlasov P.A., Warnatz, J. (2007) Detailed kinetic modeling of soot formation in shock tube pyrolysis and oxidation of toluene and n-heptane. Proceedings of the Combustion Institute 31, 575–583. http://dx.doi.org/10.1016/j.proci.2006.07.191.

Zobel, N., and Anca-Couce, A. (2013) Slow pyrolysis of wood particles: Characterization of volatiles by Laser-Induced Fluorescence. Proceedings of the Combustion Institute 34, 2355–2362 http://dx.doi.org/10.1016/j.proci.2012.06.130.

Faravelli, T., Frassoldati, A., Hemings, E.B., Ranzi, E. (2013) Multistep Kinetic Model of Biomass Pyrolysis, In Book: Cleaner Combustion, Developing Detailed Chemical Kinetic Models, Battin-Leclerc F., Simmie, J. M., Blurock, E. (Eds.), Springer-Verlag London, 111-139, http://dx.doi.org/10.1007/978-1-4471-5307-8_5.

Jones, J.M., Lea-Langton, A.R., Ma L., Pourkashanian, M., Williams, A. (2014) Combustion of Solid Biomass: Classification of Fuels, In Book: Pollutants Generated by the Combustion of Solid Biomass Fuels, Springer-Verlag London, http://dx.doi.org/10.1007/978-1-4471-6437-1.

Branco, V. and Costa, M. (2017) Effect of particle size on the burnout and emissions of particulate matter from the combustion of pulverized agricultural residues in a drop tube furnace. Energy Conversion and Management 149, 774–780 http://dx.doi.org/10.1016/j.enconman.2017.03.012.

Wang, G., Silva, R.B., Azevedo, J.L.T., Martins-Dias, S., Costa, M. (2014) Evaluation of the combustion behaviour and ash characteristics of biomass waste derived fuels, pine and coal in a drop tube furnace. Fuel 117, 809–824. http://dx.doi.org/10.1016/j.fuel.2013.09.080.

H. Bockhorn, A. D’Anna, A. F. Sarofim, H. Wang, (2009) Combustion Generated Fine Carbonaceous Particulates, Proceedings of an International Workshop held in Villa Orlandi, Anacapri, May 13-16, 2007, KIT Scientific Publishing. ISBN: 978-3-86644-441-6.

Fuzzi, S., Baltensperger, U., Carslaw, K., Decesari, S., Denier van der Gon, H., Facchini, M. C., Fowler, D., Koren, I., Langford, B., Lohmann, U., Nemitz, V., Pandis, S., Riipinen, I., Rudich, V., Schaap, M., Slowik, J. G., Spracklen, D. V., Vignati, E., Wild, M., Williams, M. and Gilardoni, S. (2015) Particulate matter, air quality and climate: lessons learned and future needs Atmos. Chem. Phys., 15, 8217–8299. http://dx.doi.org/10.5194/acp-15-8217-2015.

Dallmann, T. R., Onasch, T. B., Kirchstetter, T. W., Worton, D. R., Fortner, E. C., Herndon, S. C., Wood, E. C., Franklin, J. P., Worsnop, D. R., Goldstein, A. H., and Harley, R. A. (2014) Characterization of particulate matter emissions from on-road gasoline and diesel vehicles using a soot particle aerosol mass spectrometer. Atmos. Chem. Phys., 14, 7585–7599. http://dx.doi.org/10.5194/acp-14-7585-2014.

Wardoyo, A.Y.P., Unggul, P.J., Noor, J.A.E. (2018) Varied dose exposures to ultrafine particles in the motorcycle smoke cause kidney cell damages in male mice. Toxicology Reports 5, 383–389. http://dx.doi.org/10.1016/j.toxrep.2018.02.014.

Bruckmann, P., Birmili, W., Straub, W., Pitz, W., Gladtke, D., Pfeffer, U., Hebbinghaus, H., Wurzler, S., Olschweski, A. (2008) An outbreak of Saharan dust causing high PM10 levels north of the Alps. Gefahrstoffe Reinhaltung der Luft 68, 490-498.

Lipsky. E. M., Pekney, N. J., Walbert, G. F., O'Dowd, W. J., Freeman, M.C., Robinson. A. (2004) Effects of dilution sampling on fine particle emissions from pulverized coal combustion, Aerosol Science and Technology 38(6), 574-587. http://dx.doi.org/10.1080/02786820490479851.

Bressi, M., Sciare, J., Ghersi, V., Bonnaire, N., Nicolas, J.B., Petit, J.-E., Moukhtar, S., Rosso, A., Mihalopoulos, N., and Feron, A. (2013) A one-year comprehensive chemical characterization of fine aerosol (PM2.5) at urban, suburban and rural background sites in the region of Paris (France). Atmos. Chem. Phys. 13, 7825–7844. http://dx.doi.org/10.5194/acp-13-7825-2013.

Veleva, B., Hristova E., Nikolova, E., Kolarova, M., Valcheva, R. (2014) Seasonal variation of PM10 elemental composition in urban environment. Journal of International Scientific Publications: Ecology and Safety 8, 265-275. ISSN 1314-7234 (Online).

Manousakas, M., Diapouli, E., Papaefthymiou, H., Migliori, A., Karydas, A.G., Padilla-Alvarez, R., Bogovac, M., Kaiser, R.B., Jaksic, M., Bogdanovic-Radovic, I., Eleftheriadis K., (2015) Source apportionment by PMF on elemental concentrations obtained by PIXE analysis of PM10 samples collected at the vicinity of lignite power plants and mines in Megalopolis, Greece, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 349, 114–124. http://dx.doi.org/doi:10.1016/j.nimb.2015.02.037.

Yatkin, S., Belis, C.A., Gerboles, M., Calzolai, G., Lucarelli, F., Cavalli, F., Trzepla, K. (2016) An interlaboratory comparison study on the measurement of elements in PM10. Atmospheric Environment 125 (A), 61–68. http://dx.doi.org/10.1016/j.atmosenv.2015.10.084.

Vicente, E.D., Alves, C.A. (2018) An overview of particulate emissions from residential biomass combustion. Atmospheric Research 199, 159–185. http://dx.doi.org/10.1016/j.atmosres.2017.08.027.

Xie, Y., Zhao, B., Zhang L., Luo, R. (2015) Spatiotemporal variations of PM2.5 and PM10 concentrations between 31 Chinese cities and their relationships with SO2, NO2, CO and O3. Particuology 20, 141–149. http://dx.doi.org/10.1016/j.partic.2015.01.003.

Süring, K., Bach, S., Bossmann, K., Wolter, E., Neumann, A., Straff, W., Höflich, C. (2016) PM10 contains particle-bound allergens: Dust analysis by Flow Cytometry. Environmental Technology & Innovation, In Press, will appear in January Environmental Technology & Innovation 5, 60–66. http://dx.doi.org/10.1016/j.eti.2016.01.00.

Belis, C., Georgieva, E., Janos, O., Sega, K., Törok, S., Veleva, B., Perrone, M., Vratolis, S., Pernigotti, D., Eleftheriadis, K. A. (2015) JRS Technical Report. Comparative analysis of the causes of air pollution in three cities of the Danube region: Implications for the implementation of the air quality directives. EUR 27712 EN. doi:10.2788/73231.

Karagulian, F., Belis, C. A., Dora, C.F.C., Prüss-Ustün, A.M., Bonjour, S., Adair-Rohani, H., Amann, M. (2015) Contributions to cities' ambient particulate matter (PM): A systematic review of local source contributions at global level. Atmospheric Environment 120, 475-483. http://dx.doi.org/10.1016/j.atmosenv.2015.08.087.

Bruchmueller, J., Luo, K.H., van Wachem, B.G.M. (2013) Tar formation variations during fluidised bed pyrolytic biomass conversion. Proceedings of the Combustion Institute 34, 2373–2381. http://dx.doi.org/10.1016/j.proci.2012.06.054.

Wen, C., Xu, M., Yu, D., Sheng, C., Wuc, H., Zhang, P., Qiao, Y., Yao, H., (2013) PM10 formation during the combustion of N2-char and CO2-char of Chinese coals. Proceedings of the Combustion Institute 34, 2383–2392. http://dx.doi.org/10.1016/j.proci.2012.07.080.

Nielsen, I. E., Eriksson, A. C., Lindgren, R., Martinsson, J., Nystroem, R., Nordin, E. Z., Sadiktsis, I., Boman, C., Nøjgaard, J. K., Pagels, J. (2017) Time-resolved analysis of particle emissions from residential biomass combustion e Emissions of refractory black carbon, PAHs and organic tracers. Atmospheric Environment 165, 179-190. http://dx.doi.org/10.1016/j.atmosenv.2017.06.033.

Ahlm. L., Julin. J., Fountoukis. C., Pandis. S. N., Riipinen, I. (2013) Particle number concentrations over Europe in 2030: the role of emissions and new particle formation, Atmos. Chem. Phys. 13, 10271-10283. http://dx.doi.org/10.5194/acp-13-10271-2013.

Gadzheva, G.K., Ganeva, K.G., Miloshev, N.G., Syrakov, D. E., (2013) Prodanova, M. Numerical study of the atmospheric composition in Bulgaria. Computers and Mathematics with Applications 65, 402-422. http://dx.doi.org/10.1016/j.camwa.2012.07.002.

Fuzzi, S., Andreae, M., Huebert, B.J., Kulmula, M., Bind, T.C., Doherty, S.J., Guenther, A., Kanakidou, M., Kawamura, K., Kerminen, V.-M., Lohmann, U., Poeschl, U., Russell, L.M. (2006) Critical assessment of the current state of scientific knowledge, terminology, and research needs concerning the role of organic aerosols in the atmosphere, climate, and global change. Atmos. Chem. Phys. 6, 2017–2038. www.atmos-chem-phys.net/6/2017/2006/.

ExEA (2011-2016) Environment and Water Executive Agency, Archives of a three-monthly bulletin for the condition of the ambient air in Bulgaria, www.eea.government.bg/bg/dokladi/arhiv_trim-bul.

GREENTECH.BG - Press release (2017), https://greentech.bg/archives/70266)green.

NRSPE (2015) National Report on the Status and the Protection of the Environment of Bulgaria 2015 http://eea.government.bg/bg/soer/2013.




DOI: http://dx.doi.org/10.12955/cbup.v6.1305

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