INVESTIGATION OF INDIGO DYEING USING SODIUM BOROHYDRIDE AS REDUCING AGENT

  • Banu Yeşim Buyukakinci Engineering Faculty, Istanbul Aydın University, Istanbul, Turkey
  • Nihal Sokmen Technology Faculty, Marmara University, Istanbul, Turkey
Keywords: Indigo, dyeing, sodium borohydride, reducing agent

Abstract

Indigo, one of the oldest dyes, has a very important role for the textile sector.  It is primarily used to dye cotton clothes, and blue jeans and over one billion pairs of jeans around the world are dyed blue with indigo. Although Sodium Hydrosulfite (Na2S2O4) is used as a reducing agent in most indigo dyeing processes, it is environmentally unfavorable because of the resultant contaminated toxic wastewater. In addition, the color fastnesses of dyed samples using Na2S2O4 as reducing agent are not good enough.

In the present paper sodium borohydride (NaBH4) were used as ecologically safe reduction systems for the indigo dyeing of cotton fabric. After dyeing processes, the color yield and fastnesses according to washing and rubbing were measured, and results were compared.

It was found when NaBH4 was used as reducing agent instead of Na2S2O4, the color yield and the fastness properties of the dyed samples improved.

References

Baig G.A..(2011). Indigo dyeing of polyester (PET) – pH effects. The Journal of The Textile Institute. 102/1, 87–92.

Broadbent A.D. (2001). Basic Principles of Textile Coloration. Society of Dyers and Colourists. 376-378.

BS EN ISO 105 C06-1997, Textiles. Tests for colour fastness. Colour fastness to domestic and commercial laundering (London: BSI, 1997).

BS EN ISO 105 X12-2002, Textiles. Tests for colour fastness.Colour fastness to rubbing (London: BSI, 2002).

Dincer I, Colpan C O, Kizilkan O, Ezan M A, (2015) Progress in Clean Energy, Novel Systems and Applications, Springer, 2.

Meksi N, Kechida M, Mhenni F, (2007). Cotton dyeing by indigo with the borohydride process: Effect of some experimental conditions on indigo reduction and dyeing quality, Chemical Engineering Journal 131, 187-193

Meksi N., Ben Ticha M., Kechida M., Mhenni M. F.( 2010). New Catalysts for the Borohydride Dyeing Process, Ind. Eng. Chem. Res. 49, 12333–12338.

Tichaa mM.B., Meksia N., Driraa N., Kechidac M.F. (2013). A promising route to dye cotton by indigo with an ecological exhaustion process:A dyeing process optimization based on a response surface methodology. Industrial Crops and Products. 46, 350– 358.

Yao J., Dou C., Wei S., Zheng M. (2015). Using ecological reducing agents instead of sodium sulphide in dyeing with CI Sulphur Black. Coloration Technology. 1 131/5, 379–383.

Published
2017-09-24